Notes of Ch 2. Acids, Bases and Salts, Class 10th Science

Ch 2. Acids, Bases and Salts of Class 10th Science
       Notes of Ch 2. Acids, Bases and Salts 

                         Class 10th Science




ACIDS :-
 The term ‘acid has been derived from the Latin word, acidus, which means sour.
 Acids are those chemical substances which have a sour taste and turn blue litmus solution red. 
 According to Arrhenius concept, substances that furnish H⁺ ions in an aqueous solution are called acids.

                             Example: H₂SO₄ → 2H⁺ + SO₄²⁻
 
Properties of Acids:-

Physical Properties of Acids:-
  • Sour in taste. 
  • Change the colour of blue litmus to red.
  • Acid solution conducts electricity.
  • Give H⁺ ions in aqueous solution. 
 Chemical Properties of Acids:-
  • Reacts with metals to liberate hydrogen.  
  • Reacts with metal carbonates/metal hydrogen carbonate to liberate CO₂
  • Reacts with certain metal oxides to form salt and water.

 Natural sources of Acid :-

Substance that contain acids

Organic acid present in them

1. Orange, lemon

Citric acid, ascorbic acid (vitamin C) 

2. Apple 

Malic acid

3. Tamarind (Imli), grape

Tartaric acid

4. Olive oil 

Oleic acid

5. Vinegar

Acetic acid

6. Curd (sour milk)

Lactic acid

7. Urine 

Uric acid 

8. Tomato

Oxalic acid

9. Tea 

Tannic acid 

10. Red ants

Formic acid

11. Green leafy vegetables 

Folic acid

12. Gastric juice

Hydrochloric acid

13. Amla

Ascorbic acid 

14. Spinach

Oxalic acid

15. Bees and nettle sting

Formic acid

16. Rancid butter

Butyric acid

 
Types of Acid:-

 On the basis of their source/ occurrence acids are of two types – 
(1) Mineral acids 
(2) Organic acids

 (i) Mineral Acids:-

 Acids that are obtained from rocks and minerals are known as mineral acids. e.g., HCl, HNO, 
 Some of the commonly used mineral acid along their uses are given below as:-

Name

Type of acid

Chemical Formula 

Uses

Hydrochloric acid

Mineral Acid

HCI

Purification of NACl to make aqua regia mixture of Hu₂HNO₃ in ratio of 3 : 1, bleaching agent

Phosphoric acid

Mineral Acid

H₃PO₄

In fertilizers and in antirust paints.

Carbonic acid

Mineral Acid

H₂CO₃

Used in tanning industry, in soft drinks etc.

Sulphuric acid

Mineral Acid

H₂SO₄

Used in car batteries, in paints, plastics, drugs, in petroleum refining.

Nitric acid

Mineral Acid

HNO₃

Used in explosives manufacture like TNT and fertilizers, refining of gold and silver.


(ii) Organic Acids:-

 Acids that are present in animals and plants are called as organic acids. e.g., Lactic acid, Formic acid.
 Some of commonly used organic acids along their chemical formula with their uses are given as :-

Name

Type of acid

Chemical Formula 

Uses

Lactic acid

Organic Acid

CH₃CH(OH)COOH

Flavouring agent and food preservative. 

Organic Acid

Organic Acid

C₆H₅COOH

Used in dyes, perfumes and insect repellents, food preservative.

Benzoic acid

Organic Acid

CH₃COOH

Used as a solvent in the manufacture of dyes and perfumes, in vinegar, production of plastics. 

Organic Acid

Organic Acid

HCOOH

In tanning leather, in medicines for treating disease like gout of joints.

Citric acid

Organic Acid

C₆H₈O₇

Flavouring and preserving agent in soft drink and toffees.



Strong Acids: HCl, H2 SO4 , HNO3
Weak Acids: CH3COOH, Oxalic acid, Lactic acid
Concentrated Acids: More amount of acid + Less amount of water
Dilute Acids: More amount of water + Less amount of acid

Properties of Bases
 
Physical Properties of Bases:-
  • Bitter in taste 
  • Turn red litmus blue 
  • Give OH⁻ ions in aqueous solution 
  • Does not conduct electricity in aqueous sol”
 Chemical Properties of Bases:- 
  • Alkali reacts with metal to liberate H₂
  • Bases reacts with acidic oxides to form water.
Strong Bases: NaOH, KOH, Ca(OH)2
Weak Bases: NH4OH
Alkalis: These are bases which are soluble in water. Examples: NaOH, KOH, Ca(OH)2.

Types of Indicators and its properties

Indicators: Substances which change their colour/smell in different types of substances (like acids and bases).

Types of Indicators:

(i) Natural indicators: Litmus, red cabbage leaves extract, turmeric 
(ii) Synthetic indicators: Methyl orange, phenolphthalein etc.
(iii) Olfactory indicators: different odour in acid and bases.

Reaction of Acids and Bases with Metals

→ Reaction of Acids with Metals
• Acids react with metal to form metal salt and releases Hydrogen Gas.
Acid + Metal → Salt + Hydrogen Gas
• Example: 2HCl + Zn → ZnCl2 + H2

→ Reaction of Bases with Metals
• Bases react with metal to evolve hydrogen Gas.
Note- That all metals do not react with bases.
                Base + Metal → Salt + Hydrogen gas
 Example:  2NaOH + Zn → Na2ZnO2 + H2

Reaction of Acids with Metal Carbonates and Metal Hydrogencarbonates

• Acids reacts with Metal Carbonates and Metal Hydrogencarbonates to form Salt, Carbon dioxide and water.
Metal carbonate/Metal hydrogen carbonate + Acid → Salt + Carbon dioxide + Water
   Examples: (i) 2HCl + Na2CO3 → 2NaCl + CO2 + H2O
                    (ii) HCl + NaHCO3 → NaCl + CO2 + H2O
                    (iii) Ca(OH)2 + CO2 → CaCO3 + H2O
 
 • When excess CO2 is passed, milkiness disappears.
                 CaCO3 + CO2 + H2O → Ca(HCO)3
 
• Bases do not react with Metal Carbonates and Metal Hydrogencarbonates.

 Base + Metal Carbonate/Metal Hydrogen Carbonate → No Reaction

Reaction of Acids and Bases with each other

• Acids and Bases react to form salt and water.
Acid + Base → Salt + H2O

• Neutralisation Reaction: Reaction of acid with a base is called as neutralization reaction.
Example: HCl + NaOH → NaCl + H2O
Example: HCl + NaOH → NaCl + H2O
• Strong Acid + Weak Base → Acidic salt + H2O
• Weak Acid + Strong Base → Basic salt + H2O
• Strong Acid + Strong Base → Neutral salt + H2O
• Weak Acid + Weak Base → Neutral salt + H2O

Reaction of Metallic Oxides with Acids

→ Metallic oxides are basic in nature.
Example: CaO, MgO are basic oxides.
                  Metallic Oxide + Acid → Salt + H2O
                  CaO + 2HCl → CaCl2 + H2O

Reaction of Non-metallic Oxides with Bases

→ Non-metallic oxides are acidic in nature.
→ Non-metallic Oxide + Base → Salt + H2O
CO2 + Ca(OH)2 → CaCO3 + H2O

Reaction of Acid
  (i) Acid + Metal Carbonate → Salt + CO2 + Water
  (ii) Acid + Metal → Salt + H2
  (iii) Acid + Metal Hydrogen Carbonate → Salt + CO2 + H2O
  (iv) Acid + Metallic oxide → Salt +H2O
  (v) Acid + Base → Salt + H2O

Reaction of Base
      (i) Base + Metal → Salt + H2
     (ii) Base + Metal Carbonate → No Reaction
     (iii) Base + Metal Hydrogen Carbonate → No Reaction
     (iv) Base + Acid → Salt + H2O
     (v) Base + Non Metallic oxide → Salt + H2O

Similarities between all Acids and all Bases
→ All acids have H+ ions in common. All acids produce H+ ions
→ Acids produce H+ ions in solution which are responsible for their acidic properties.
→ All bases have OH- (hydroxyl ions) in common. All bases produce OH- ions

Acid or Base in Water Solution
→ Acids produce H+ ions in presence of water.
→ H+ ions cannot exist alone, they exist as H3O+ (hydronium ions).
                   H+ + H2O → H3O+
                   HCl + H2O → H3O+ + Cl-
→ Bases when dissolved in water gives OH − ions.
           
→ Bases soluble in water are called alkali.

Strength of Acids and Base solutions
→ Strength of acid or base can be estimated using universal indicator.

 Universal indicator: It is a mixture of several indicators. It shows different colours at different concentrations of H+ ions in the solution.

 pH Scale: A scale for measuring H+ ion concentration in a solution. p in pH stands for ‘potenz’ a German word which means power.

               • If value of ph is equal to 7 → neutral solution
               • If value of pH is less than 7 → acidic solution
               • If value of pH more than 7 → basic solution

                                                        The End